Highly Efficient, Selective, and General Method for the Preparation of Meridional Homo- and Heteroleptic Tris-cyclometalated Iridium Complexes
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A highly efficient and general method based on transmetalation with an organozinc reagent is developed for selective preparation of homo- and heteroleptic meridional tris-cyclometalated iridium complexes. The molecular structure of mer-Ir(1-piq)2(ppy) (2) has been determined by a single-crystal X-ray diffraction analysis. The emission properties of a series of meridional complexes are reported.
创建时间:
2016-05-05



