Catalyst-Enabled Scaffold Diversity: Highly Chemo- and Stereoselective Synthesis of Tricyclic Ketals and Triarylmethanes
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https://figshare.com/articles/dataset/Catalyst-Enabled_Scaffold_Diversity_Highly_Chemo-_and_Stereoselective_Synthesis_of_Tricyclic_Ketals_and_Triarylmethanes/5209297
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资源简介：
The first catalytic
cascade reaction of activated isocyanides with para-quinone methide-aryl esters is presented. Catalyst-enabled
divergent pathways have also been achieved to deliver skeletally diverse
products. While Ag catalysis leads to an unprecedented highly diastereoselective
synthesis of tricyclic ketals, a simple procedure employing Cu catalysis
produces oxazole-containing triarylmethanes in high efficiency through
an unexpected C–C bond cleavage.
创建时间：
2017-07-14
