One-Pot Synthesis of [(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>BH<sub>2</sub>]<sup>−</sup> from C<sub>6</sub>F<sub>5</sub>MgBr/BH<sub>3</sub>·SMe<sub>2</sub> and Its in Situ Transformation to Piers’ Borane
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Depending on the crystallization procedure, the one-pot reaction between 2 C6F5MgBr, 1 BH3·SMe2, and 1 Me3SiCl furnishes the hydridoborate salts [Mg2(Et2O)3Br2Cl][(C6F5)2BH2] and [Mg(Et2O)2][(C6F5)2BH2]2, both of which are convenient starting materials for the in situ generation of Piers’ borane (C6F5)2BH.
创建时间：
2011-05-23
