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Crystallographic Evidence of a Base-Free Uranium(IV) Terminal Oxo Species

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NIAID Data Ecosystem2026-03-06 收录
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The uranium(IV) terminal oxo species Tp*2U(O) has been synthesized by oxygen-atom transfer from pyridine-N-oxide to Tp*2U(2,2′-bipyridine), a trivalent uranium species with a monoanionic bipyridine ligand. Full characterization of the oxo species using 1H NMR and IR spectroscopies, X-ray crystallography, and computational studies was performed.

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2016-02-24
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