Exploration of the Mechanism of Platinum(II)-Catalyzed C–F Activation: Characterization and Reactivity of Platinum(IV) Fluoroaryl Complexes Relevant to Catalysis
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https://figshare.com/articles/dataset/Exploration_of_the_Mechanism_of_Platinum_II_Catalyzed_C_F_Activation_Characterization_and_Reactivity_of_Platinum_IV_Fluoroaryl_Complexes_Relevant_to_Catalysis/2546896
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资源简介：
A series of Pt(IV) complexes relevant to catalytic C–F
activation
have been prepared and structurally characterized. PtIV–F complexes, formed by C–F activation, underwent transmetalation
with Me2Zn to generate Me3PtIV fluoroaryl
complexes. In all cases, the Me3PtIV complex
underwent reductive elimination to generate methylated organic products.
The reactivity of both PtIV–F and Me3PtIV fluoroaryl complexes was strongly affected by the
electronic nature of the cyclometalated fluoroaryl ligand.
创建时间：
2016-02-22
