Rhodium(III)-Catalyzed Intermolecular Amidation with Azides via C(sp<sup>3</sup>)–H Functionalization
收藏NIAID Data Ecosystem2026-03-08 收录
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资源简介：
The amidation reactions of 8-methylquinolines with azides catalyzed by a cationic rhodium(III) complex proceed efficiently to give quinolin-8-ylmethanamine derivatives in good yields via C(sp3)–H bond activation under external oxidant-free conditions. A catalytically competent five-membered rhodacycle has been isolated and characterized, revealing a key intermediate in the catalytic cycle.
创建时间：
2016-02-17
