Assembly of Cerium(III) 2,2′-Bipyridine-5,5′-dicarboxylate-based Metal–Organic Frameworks by Solvent Tuning
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https://figshare.com/articles/dataset/Assembly_of_Cerium_III_2_2_Bipyridine_5_5_dicarboxylate_based_Metal_Organic_Frameworks_by_Solvent_Tuning/2278519
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资源简介：
Small
changes to the reaction conditions differentiate between
two metal–organic frameworks (MOFs), {[Ce2(H2O)(bpdc)3(dmf)2]·2(dmf)}n (1) and {[Ce4(H2O)5(bpdc)6(dmf)]·x(dmf)}n (2), that were solvothermally
synthesized from cerium(III) nitrate hexahydrate and 2,2′-bipyridine-5,5′-dicarboxylic
acid (H2bpdc) in dimethylformamide (dmf). The two compounds
illustrate how the flexibility of the coordination geometry of CeIII translates into MOFs, the formation of which readily adapts
to different solvent environments.
创建时间：
2016-02-17
