Concise Approach to the Carbocyclic Core of the Naturally Occurring Sphingomyelinase Inhibitor Scyphostatin
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https://figshare.com/articles/dataset/Concise_Approach_to_the_Carbocyclic_Core_of_the_Naturally_Occurring_Sphingomyelinase_Inhibitor_Scyphostatin/2426668
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资源简介：
A flexible strategy toward the carbocyclic
core of the naturally
occurring sphingomyelinase inhibitor scyphostatin, from the readily
available Diels–Alder adducts of cyclopentadiene and 2-allyl-p-benzoquinone, has been devised. This approach leverages
the stereochemical predisposition of the norbornyl-fused scaffolds
to generate the desired stereochemical pattern and leads to a concise
synthesis of the epoxycyclohexenoid core of scyphostatin with a manipulable
allyl side arm.
创建时间：
2016-02-19
