Aminodiols via Stereocontrolled Oxidation of Methyleneaziridines
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https://figshare.com/articles/dataset/Aminodiols_via_Stereocontrolled_Oxidation_of_Methyleneaziridines/2030460
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资源简介:
A highly
diastereoselective Ru-catalyzed oxidation/reduction sequence
of bicyclic methyleneaziridines provides a facile route to complex
1-amino-2,3-diol motifs. The relative anti stereochemistry
between the amine and the vicinal alcohol are proposed to result from
1,3-bischelation in the transition state by the C1 and C3 heteroatoms.
创建时间:
2015-12-17



