Aminodiols via Stereocontrolled Oxidation of Methyleneaziridines
收藏NIAID Data Ecosystem2026-03-09 收录
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A highly diastereoselective Ru-catalyzed oxidation/reduction sequence of bicyclic methyleneaziridines provides a facile route to complex 1-amino-2,3-diol motifs. The relative anti stereochemistry between the amine and the vicinal alcohol are proposed to result from 1,3-bischelation in the transition state by the C1 and C3 heteroatoms.
创建时间:
2015-12-17



