Formation of Bridging Alkene and Conjugated Dialkenes Exclusively Generated from Alkynes on the [3,3‘-Co(1,2-C<sub>2</sub>B<sub>9</sub>H<sub>11</sub>)<sub>2</sub>]<sup>-</sup> Platform. The Unique Hydroboration Role of [3,3‘-Co(1,2-C<sub>2</sub>B<sub>9</sub>H<sub>11</sub>)<sub>2</sub>]<sup>-</sup>
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数据链接:
https://figshare.com/articles/dataset/Formation_of_Bridging_Alkene_and_Conjugated_Dialkenes_Exclusively_Generated_from_Alkynes_on_the_3_3_Co_1_2_C_sub_2_sub_B_sub_9_sub_H_sub_11_sub_sub_2_sub_sup_sup_Platform_The_Unique_Hydroboration_Role_of_3_3_Co_1_2_C_sub_2_sub_B_sub_9_sub_H_sub_11_sub_sub/3357694数据链接链接失效反馈
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资源简介:
The unprecedented metal-mediated transformation of an alkyne into a B,B‘ bridging alkene is reported. Also, the unprecedented synthesis of a conjugated dialkene derivative of [3,3‘-Co(1,2-C2B9H11)2]- generated only from an alkyne, contrary to the usual case where an alkyne and an alkene are needed, is described. This has been possible through the singular capacity of a B−H to produce hydroboration.
创建时间:
2016-05-07



