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Formation of Bridging Alkene and Conjugated Dialkenes Exclusively Generated from Alkynes on the [3,3‘-Co(1,2-C<sub>2</sub>B<sub>9</sub>H<sub>11</sub>)<sub>2</sub>]<sup>-</sup> Platform. The Unique Hydroboration Role of [3,3‘-Co(1,2-C<sub>2</sub>B<sub>9</sub>H<sub>11</sub>)<sub>2</sub>]<sup>-</sup>

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NIAID Data Ecosystem2026-03-06 收录
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The unprecedented metal-mediated transformation of an alkyne into a B,B‘ bridging alkene is reported. Also, the unprecedented synthesis of a conjugated dialkene derivative of [3,3‘-Co(1,2-C2B9H11)2]- generated only from an alkyne, contrary to the usual case where an alkyne and an alkene are needed, is described. This has been possible through the singular capacity of a B−H to produce hydroboration.

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2016-05-07
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