Platinum(II) Chloride-Catalyzed Stereoselective Domino Enyne Isomerization/Diels−Alder Reaction
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Chiral 1,6-enynes were prepared via Ir-catalyzed allylic substitutions. Their platinum(II) chloride-catalyzed domino enyne isomerization/Diels−Alder reaction provided stereoselective access to complex heterocycles. Very high diastereoselectivity was induced by a chirality center of the enyne.
创建时间：
2010-11-19
