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Biomimetic Synthesis of ent-(−)-Azonazine and Stereochemical Reassignment of Natural Product

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Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Biomimetic_Synthesis_of_i_ent_i_Azonazine_and_Stereochemical_Reassignment_of_Natural_Product/2379883
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The first total synthesis of ent-(−)-azonazine has been accomplished using a hypervalent iodine-mediated biomimetic oxidative cyclization to construct the highly strained core. Based on the results from the completed synthesis, both the relative and absolute configurations of natural (+)-azonazine were revised.
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2016-02-18
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