K<sub>8</sub>(K<sub>5</sub>F)U<sub>6</sub>Si<sub>8</sub>O<sub>40</sub>: An Intergrowth Uranyl Silicate
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Single crystals of K8(K5F)U6Si8O40 were grown from a mixed alkali halide flux. K8(K5F)U6Si8O40 is the first intergrowth uranyl silicate, being composed of alternating slabs related to two previously reported uranyl silicates: Cs2USiO6 and [Na9F2][(UO2)(UO2)2(Si2O7)2]. It exhibits intense luminescence, which is influenced by the [(UO2)2O] dimers present in the structure.
创建时间:
2016-03-29



