1,2-Dioxines Containing Tethered Hydroxyl Functionality as Convenient Precursors for Pyran Syntheses
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https://figshare.com/articles/dataset/1_2_Dioxines_Containing_Tethered_Hydroxyl_Functionality_as_Convenient_Precursors_for_Pyran_Syntheses/3262921
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资源简介:
A new method for the construction of tetrahydropyrans derived from readily available 1,2-dioxines
containing a tethered hydroxyl moiety is described. The reaction proceeds via a base-catalyzed
rearrangement of the 1,2-dioxines to either the isomeric cis or trans γ-hydroxy enones followed by
intramolecular oxa-Michael addition of the tethered hydroxyl group.
创建时间:
2016-05-05



