LDA-Mediated Selective Addition Reaction of Vinylidenecyclopropanes with Aldehydes, Ketones, and Enones: Facile Synthesis of Vinylcyclopropenes, Allenols, and 1,3-Enynes
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https://figshare.com/articles/dataset/LDA_Mediated_Selective_Addition_Reaction_of_Vinylidenecyclopropanes_with_Aldehydes_Ketones_and_Enones_Facile_Synthesis_of_Vinylcyclopropenes_Allenols_and_1_3_Enynes/2939095
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资源简介:
Highly selective addition reaction of vinylidenecyclopropanes 1 was realized by treatment with LDA in THF and quenching with aldehydes, ketones, and enones. A number of vinylcyclopropenes, allenols, and 1,3-enynes were obtained selectively in moderate to good yields depending on the nature of different electrophiles.
创建时间:
2016-02-27



