Reactions of Imines with Azazirconacyclobutenes and Generation of Electron-Deficient Imidozirconocene Complexes
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https://figshare.com/articles/dataset/Reactions_of_Imines_with_Azazirconacyclobutenes_and_Generation_of_Electron_Deficient_Imidozirconocene_Complexes/3340195
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资源简介:
Electron-deficient imines are shown to insert
into the zirconium−carbon bond of azazirconacyclobutenes
to generate new six-membered ring metallacycles. On
heating, these expanded zirconacycles undergo a retro-[4 + 2] cycloaddition to generate α,β-unsaturated imines
in excellent yields and novel, fully characterized electron-deficient imidozirconocene complexes.
创建时间:
2004-05-10



