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Reactions of Imines with Azazirconacyclobutenes and Generation of Electron-Deficient Imidozirconocene Complexes

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Reactions_of_Imines_with_Azazirconacyclobutenes_and_Generation_of_Electron_Deficient_Imidozirconocene_Complexes/3340195
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资源简介:
Electron-deficient imines are shown to insert into the zirconium−carbon bond of azazirconacyclobutenes to generate new six-membered ring metallacycles. On heating, these expanded zirconacycles undergo a retro-[4 + 2] cycloaddition to generate α,β-unsaturated imines in excellent yields and novel, fully characterized electron-deficient imidozirconocene complexes.
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2004-05-10
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