Crystalline Tetraatomic Boron(0) Species
收藏NIAID Data Ecosystem2026-03-11 收录
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https://figshare.com/articles/dataset/Crystalline_Tetraatomic_Boron_0_Species/7889672
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资源简介：
Reaction of a 1,2-diboraallene 1 with tetradibromodiborane
B2Br4 coordinated by a cyclic (alkyl)(amino)carbene
(cAAC) in a 3:1 ratio affords a neutral tetraboron species 2 that possesses a planar tetraatomic boron(0) unit with the average
oxidation state of zero. X-ray diffraction analysis and computational
studies indicate that 2 features the delocalized electrons
in the part of the σ-framework of the B4 unit, as
well as the conjugated π-system over the C–B3–C moiety.
创建时间：
2019-03-25
