The in-situ study of novel heterometallic metal organic framework structural response to the CO2 uptake
收藏ESRF Portal2028-01-01 更新2026-04-23 收录
下载链接：
https://doi.esrf.fr/10.15151/ESRF-ES-2148342620
下载链接
链接失效反馈官方服务：
资源简介：
Metal organic frameworks (MOFs) are crystalline porous hybrid materials which adopt large chemical and structural diversity with various types of porous structures and functionalities. They have attracted much attention for various practical applications in particular for post-combustion capture of flue gas emitted from power plants. We propose the in-situ powder X-ray diffraction (PXRD) study of CO2 uptake by the novel ultra-microporous heterometallic MIP-212 (MIP stands for the Materials of the Institute of Porous Materials from Paris). Cu-based chains in MIP-212 coordinate water, which upon the activation (above 230 ˚C) create active open metal sites capable to attract CO2 at relatively low pressures with a total uptake comparable with some of the benchmark MOFs reported to date. The PXRD will allow to investigate the crystal structure response/flexibility of MIP-212(Al-Cu) to the CO2 loading depending on the activation conditions and rationalize the mechanism of its uptake.
提供机构：
Ecole Normale Superieure, Institut des Matériaux Poreux de Paris, 24 Rue Lhomond, 75005, Paris, FRANCE; EPFL Valais, LSMO, Institute of Chemical Sciences & Engineering, Rue De L’industrie 17, 1951 Sion, Switzerland; Ecole Normale Superieure, Institut des Matériaux Poreux de Paris, 24 Rue Lhomond, 75005 Paris, France
创建时间：
2028-01-01
