Enantioselective Synthesis of Masked Benzoquinones Using Designer Chiral Hypervalent Organoiodine(III) Catalysis
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https://figshare.com/articles/dataset/Enantioselective_Synthesis_of_Masked_Benzoquinones_Using_Designer_Chiral_Hypervalent_Organoiodine_III_Catalysis/4497494
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资源简介：
A highly
enantioselective oxidative dearomatization of ortho- and para-hydroquinone derivatives
to the corresponding masked ortho- and para-benzoquinones has been achieved by using chiral organoiodine(III)
catalysts. Importantly, the remote steric effects of the hydrogen-bonding
designer organoiodine catalysts allowed us to achieve high chemo-
and enantioselectivity for the oxidative dearomatization of para-hydroquinone derivatives through an associative iodine(III)–phenoxide
intermediate.
创建时间：
2016-12-27
