A Monolithiated and Its Related 1,3-Dilithiated Allylsilane: Syntheses, Crystal Structures, and Reactivity
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/A_Monolithiated_and_Its_Related_1_3_Dilithiated_Allylsilane_Syntheses_Crystal_Structures_and_Reactivity/3073789
下载链接
链接失效反馈官方服务：
资源简介：
Treatment of Me2Si(CH2CHCH2)(CH2NC5H10) with 1 or 2 equiv of t-BuLi afforded the mono- or dilithiated allylsilanes, which crystallize as a tetramer and a hexamer from pentane. The product selectivity in trapping reactions is influenced by the ability of both the solvent and the electrophile to coordinate the lithium center.
创建时间：
2016-03-01
