Diastereoselective Synthesis of Complex cis-Hexahydroindanes by Reductive Alkylation
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https://figshare.com/articles/dataset/Diastereoselective_Synthesis_of_Complex_i_cis_i_Hexahydroindanes_by_Reductive_Alkylation/2418811
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An efficient and operationally simple approach to complex cis-hexahydroindanes is reported. Upon Birch reduction of unprotected, C4-alkylated tetrahydroindanols and electrophilic trapping of the tetrasubstituted enolate, cis-fused products are formed with a new stereogenic quaternary carbon. The reaction is convergent, completely diastereoselective, and shows a broad scope with regard to the electrophile.
创建时间：
2016-02-19
