NHC Gold(III) Triflimidate Complexes
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https://figshare.com/articles/dataset/NHC_Gold_III_Triflimidate_Complexes/2506960
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资源简介:
Substitution of a trans chloride ligand in the N-heterocyclic
carbene
(NHC) AuIII complexes (NHC)AuCl3 in the presence
of AgNTf2 yields a new family of (NHC)AuCl2(NTf2) complexes. They display a moderate stability in solution
but are stable once crystallized. These new organogold(III) complexes
could be fully characterized by NMR, IR, and single crystal X-ray
diffraction. They exhibit in 13C{1H} NMR an
unusually upfield-shifted resonance associated with the carbene center.
创建时间:
2016-02-20



