Concomitant Reactivity of the m-Terphenylindium Dihydroxide [2,6-Mes2C6H3In(OH)2]4 toward Carbon Dioxide and Ethylene Glycol
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https://figshare.com/articles/dataset/Concomitant_Reactivity_of_the_i_m_i_Terphenylindium_Dihydroxide_2_6_Mes_sub_2_sub_C_sub_6_sub_H_sub_3_sub_In_OH_sub_2_sub_sub_4_sub_toward_Carbon_Dioxide_and_Ethylene_Glycol/2523124
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The stepwise reaction of [2,6-Mes2C6H3In(OH)2]4 with carbon dioxide and ethylene glycol proceeded with the formation of (2,6-Mes2C6H3In)4(CO3)2(OH)4(H2O)2 (1) and (2,6-Mes2C6H3In)4(OCH2CH2O)2(OH)4 (2), respectively, and eventually produced (2,6-Mes2C6H3In)4(CO3)2(OCH2CH2OH)2(OH)2 (3). Attempts to liberate ethylene carbonate upon heating of 3 were unsuccessful.
创建时间:
2016-02-20



