Synthesis and Characterization of <i>N</i>-[2-P(<i>i</i>-Pr)<sub>2</sub>-4-methylphenyl]<sub>2</sub><sup>–</sup> (PNP) Pincer Tin(IV) and Tin(II) Complexes
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N-[2-P(i-Pr)2-4-methylphenyl]2– (PNP) pincer complexes of tin(IV) and tin(II), [(PNP)SnCl3] (2) and [(PNP)SnN(SiMe3)2] (3), respectively, were prepared and characterized by X-ray diffraction, solution and solid state NMR spectroscopy, and 119Sn Mössbauer spectroscopy. Furthermore, 119Sn cross polarization magic angle spinning NMR spectroscopic data of [Sn(NMe2)2]2 are reported. Compound 2 is surprisingly stable toward air, but attempts to substitute chloride ligands caused decomposition.
创建时间：
2016-02-20
