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Dithiodiolate Ligands: Group 4 Complexes and Application in Lactide Polymerization

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https://figshare.com/articles/dataset/Dithiodiolate_Ligands_Group_4_Complexes_and_Application_in_Lactide_Polymerization/2772901
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Dithiodiolate ligands were synthesized by reacting 1,2-ethanedithiol or 1,2-benzenedithiol with 2,2-bis(trifluoromethyl)oxirane, led selectively to mononuclear octahedral group 4 complexes of the type [{OSSO}M(OR)2], which features C2 symmetry and fluxional behavior, and were highly active in the ring-opening polymerization of rac- and l-lactide.
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2010-05-03
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