From 3‑Fold Completive Self-Sorting of a Nine-Component Library to a Seven-Component Scalene Quadrilateral

Three-fold completive self-sorting of a nine-component library with ≥126 possible combinations led to the clean formation of only three heteroleptic metal–ligand complexes. Due to the orthogonality of the latter, they were used as corner stones in an integrative self-sorting approach toward a seven-component scalene quadrilateral.