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Boroxide Complexes of the Group 4 Metals: A “Noninnocent” Ligand in Olefin Polymerization †
The synthesis of a series of group 4 metal complexes supported by the boroxide anion, [OB(mes)2]-, is described and their application in α-olefin polymerization discussed. The compounds M{OB(mes)2}2Cl
NIAID Data Ecosystem80
Formation of Acene-Based Polymers: Mechanistic Computational Study
Understanding the mechanism of linear acene decomposition and its reactivity is a prerequisite for controlling the stability of acenes and their future applications. Previously, we suggested that long
Figshare2016-02-18 更新30
Synthesis of Mixed NHC/L Platinum(II) Complexes: Restricted Rotation of the NHC Group
The use of (NHC)AgX salts as transmetallating agents for platinum can be tuned to introduce either one or two NHC ligands per platinum in high yield. Complexes with a single NHC ligand are prepared wi
Figshare2007-12-03 更新20
Synthesis, Structure, and Bridge-Terminal Exchange Kinetics of Pyrazolate-Bridged Digallium and Diindium Complexes Containing Bridging Phenyl Groups
Treatment of triphenylgallium with 3,5-dimethylpyrazole, 3,5-diphenylpyrazole, or 3,5-di-tert-butylpyrazole in a 2:1 stoichiometry afforded the phenyl-bridged complexes (C6H5)2Ga(μ-Me2pz)(μ-C6H5)Ga(C6
NIAID Data Ecosystem40
Activation of Molecular Oxygen by a Molybdenum(IV) Imido Compound
Activation of molecular dioxygen at a molybdenum(IV) imido compound led to the isolation and full characterization of a remarkably stable transition-metal imidoperoxido complex.
NIAID Data Ecosystem30
