Bulky N‑Phosphino-Functionalized N‑Heterocyclic Carbene Ligands: Synthesis, Ruthenium Coordination Chemistry, and Ruthenium Alkylidene Complexes for Olefin Metathesis
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https://figshare.com/articles/dataset/Bulky_N_Phosphino_Functionalized_N_Heterocyclic_Carbene_Ligands_Synthesis_Ruthenium_Coordination_Chemistry_and_Ruthenium_Alkylidene_Complexes_for_Olefin_Metathesis/2115961
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资源简介：
Ruthenium
chemistry and applications in catalytic olefin metathesis based on
N-phosphino-functionalized N-heterocyclic carbene ligands (NHCPs)
are presented. Alkyl NHCP Ru coordination chemistry is described,
and access to several potential synthetic precursors for ruthenium
alkylidene complexes is outlined, incorporating both trimethylsilyl
and phenyl alkylidenes. The Ru alkylidene complexes are evaluated
as potential olefin metathesis catalysts and were shown to behave
in a latent fashion. They displayed catalytic activity at elevated
temperatures for both ring closing metathesis and ring opening metathesis
polymerization.
创建时间：
2016-02-12
