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Synthesis and Optical Properties of Stable Gallafluorene Derivatives: Investigation of Their Emission via Triplet States

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NIAID Data Ecosystem2026-03-09 收录
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We designed and synthesized air- and moisture-stable gallafluorenes in which two benzene rings were bridged by the four-coordinate gallium atoms. The series of gallafluorenes were prepared by introducing electron-donating and -withdrawing groups through Suzuki–Miyaura coupling reactions. The gallafluorenes showed unique emissions via their triplet states in the presence of B­(C6F5)3. These emissions were obtained via the triplet exciplex of gallafluorene and B­(C6F5)3.

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2016-02-19
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