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Synthesis of α‑Substituted Enoximes with Nucleophiles via Nitrosoallenes

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NIAID Data Ecosystem2026-03-09 收录
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This paper reports nitrosoallene-mediated synthesis of α-substituted enoximes. Nucleophilic substitution of nitrosoallenes, a novel chemical species prepared from allenyl N-hydroxysulfonamides, afforded α-functionalized enoximes. Introduction of various nucleophiles proceeded smoothly to form C–N, C–O, C–S, C–F, and C–C bonds in the presence of azodicarboxylates.

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2016-02-12
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