Fluoroalkylative Aryl Migration of Conjugated N‑Arylsulfonylated Amides Using Easily Accessible Sodium Di- and Monofluoroalkanesulfinates
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Fluorinated sulfinate salts RfSO2Na (Rf = CF2H, CF2Ph, and CH2F) have been prepared via NaBH4-mediated reduction of the corresponding benzo[d]thiazol-2-yl sulfones, and their synthetic application as di- and monofluoroalkyl radical precursors is demonstrated in the silver-catalyzed cascade fluoroalkylation/aryl migration/SO2 extrusion of conjugated N-arylsulfonylated amides.
创建时间：
2015-12-17
