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A Thiophosphinidene Complex as a Vehicle in Phosphinidene Transmetalation: Easy Formation and Cleavage of a P–S Bond

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Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Thiophosphinidene_Complex_as_a_Vehicle_in_Phosphinidene_Transmetalation_Easy_Formation_and_Cleavage_of_a_P_S_Bond/2589100
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A method for the generation of transition metal–phosphorus multiple bonds has been developed using the reactions of a novel thiophosphinidene-bridged dimolybdenum complex with different metal carbonyls. The overall process could be considered as a transmetalation of the phosphinidene ligand involving the activation of P–S and P–Mo bonds.
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2016-02-22
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