Rh(I)/(III)-N-Heterocyclic Carbene Complexes: Effect of Steric Confinement Up...
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Novel Rh(III) pentamethylcyclopentadienyl and Rh(I) complexes containing chelating N-heterocyclic carbenes have been prepared and used in the hydrosilylation of 1-alkynes....
本研究已成功制备含螯合型氮杂环卡宾(N-heterocyclic carbenes)的新型三价铑(Rh(III))五甲基环戊二烯基(pentamethylcyclopentadienyl)配合物与一价铑(Rh(I))配合物,并将其应用于1-炔烃的硅氢化反应(hydrosilylation)中……



