Successive Formation of Hydrido(germyl)platinum, Germaplatinacycle, and Germylene-Bridged Dinuclear Platinum Complexes from the Reaction of a Zerovalent Platinum Complex with α,ω-Dihydrodigermanes
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Successive_Formation_of_Hydrido_germyl_platinum_Germaplatinacycle_and_Germylene_Bridged_Dinuclear_Platinum_Complexes_from_the_Reaction_of_a_Zerovalent_Platinum_Complex_with_Dihydrodigermanes/3270979
下载链接
链接失效反馈官方服务：
资源简介：
The reaction of Pt(η2-C2H4)(PPh3)2 (1) with
HPh2Ge(SiMe2)nGePh2H (2; n = 0−3) initially forms the
hydrido(germyl)platinum complex cis-Pt(H)[GePh2(SiMe2)nGePh2H](PPh3)2 (3), followed by the generation
of the cyclic bis(germyl)platinum complex (4) and finally formation of a
dinuclear platinum complex with bridging diphenylgermyl ligands containing a Pt−Pt bond, [Pt(μ-GePh2)(PPh3)]2 (5). The structures of 4 (n = 2) and 5 were
determined by X-ray crystallography.
创建时间：
2016-05-05
