Discovery and Mechanistic Study of a Totally Organic C(aryl)–C(alkyl)Oxygen Insertion Reaction
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https://figshare.com/articles/dataset/Discovery_and_Mechanistic_Study_of_a_Totally_Organic_C_sub_aryl_sub_C_sub_alkyl_sub_Oxygen_Insertion_Reaction/9976541
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We report an unprecedented photochemical oxygen insertion reaction into an aromatic quinone methide. Insertion happens specifically within a C(aryl)–C(alkyl) bond, whereas the quinone methide moiety remains intact itself. Detailed mechanistic studies, supported by DFT calculations, support a pathway in which the p-QM plays a pivotal activating role.
创建时间：
2019-10-02
