Asymmetric Synthesis of Glutamic Acid Derivatives by Silver-Catalyzed Conjugate Addition–Elimination Reactions
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https://figshare.com/articles/dataset/Asymmetric_Synthesis_of_Glutamic_Acid_Derivatives_by_Silver-Catalyzed_Conjugate_Addition_Elimination_Reactions/5352763
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资源简介：
The
enantioselective construction of a family of chiral glycine-derived
aldimino esters is described. The asymmetric tandem conjugate addition–elimination
procedure is characterized by its exceptional mild reaction conditions
and features with an exquisite enantioselectivity profile using commercially
available silver/DTBM-SegPhos catalyst, allowing for the facile preparation
of a variety of substituted and chiral glutamic acid derivatives (up
to 99% ee) bearing Schiff base in a straightforward manner.
创建时间：
2017-08-28
