Nickel-Catalyzed One-Pot Tandem 1,4-1,2-Addition of P(O)H Compounds to 1,10-Phenanthrolines
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https://figshare.com/articles/dataset/Nickel_Catalyzed_One_Pot_Tandem_1_4_1_2_Addition_of_P_O_H_Compounds_to_1_10_Phenanthrolines/2215000
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资源简介:
A novel
and efficient nickel-catalyzed tandem 1,4-1,2-addition
of P(O)H compounds to 1,10-phenanthrolines forming various 2,4-diphosphono-1,2,3,4-tetrahydro-1,10-phenanthrolines
has been developed. This reaction breaks up the aromatic stabilization
and directly introduces two phosphorus moieties in one single step.
This finding is the first example of transition-metal-catalyzed double
hydrophosphonylation of 1,10-phenanthrolines.
创建时间:
2015-01-16



