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Nickel-Catalyzed One-Pot Tandem 1,4-1,2-Addition of P(O)H Compounds to 1,10-Phenanthrolines

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下载链接:
https://figshare.com/articles/dataset/Nickel_Catalyzed_One_Pot_Tandem_1_4_1_2_Addition_of_P_O_H_Compounds_to_1_10_Phenanthrolines/2215000
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资源简介:
A novel and efficient nickel-catalyzed tandem 1,4-1,2-addition of P­(O)H compounds to 1,10-phenanthrolines forming various 2,4-diphosphono-1,2,3,4-tetrahydro-1,10-phenanthrolines has been developed. This reaction breaks up the aromatic stabilization and directly introduces two phosphorus moieties in one single step. This finding is the first example of transition-metal-catalyzed double hydrophosphonylation of 1,10-phenanthrolines.
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2015-01-16
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