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Synthesis of Oxosumanenes through Benzylic Oxidation

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Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_Oxosumanenes_through_Benzylic_Oxidation/2605165
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Oxosumanenes were synthesized through benzylic oxidation. The electronic and redox properties were revealed to exhibit the expanded π-conjugation compared to sumanene. Single-crystal X-ray analysis of monooxosumanene showed columnar π-stacking in a concave–convex fashion. Stereoselective trimethylation of the trioxo derivative was performed via 1,2-addition to the carbonyl groups.
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2016-02-22
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