Synthesis of Oxosumanenes through Benzylic Oxidation
收藏NIAID Data Ecosystem2026-03-07 收录
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Oxosumanenes were synthesized through benzylic oxidation. The electronic and redox properties were revealed to exhibit the expanded π-conjugation compared to sumanene. Single-crystal X-ray analysis of monooxosumanene showed columnar π-stacking in a concave–convex fashion. Stereoselective trimethylation of the trioxo derivative was performed via 1,2-addition to the carbonyl groups.
创建时间：
2011-10-07
