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Efficient Synthesis and Structural Characteristics of Zwitterionic Twisted π-Electron System Biaryls

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https://figshare.com/articles/dataset/Efficient_Synthesis_and_Structural_Characteristics_of_Zwitterionic_Twisted_Electron_System_Biaryls/3272536
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A series of unconventional twisted π-electron system molecules has been synthesized via Suzuki cross-coupling of two sterically hindered arenes. Crystallographic analysis of these molecules reveals a large ring−ring dihedral twist angle (87°) and a highly charge-separated zwitterionic ground state. An efficient conversion of phenols into aryl halides is also reported.
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2005-08-18
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