Efficient Synthesis and Structural Characteristics of Zwitterionic Twisted π-Electron System Biaryls
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A series of unconventional twisted π-electron system molecules has been synthesized via Suzuki cross-coupling of two sterically hindered arenes. Crystallographic analysis of these molecules reveals a large ring−ring dihedral twist angle (87°) and a highly charge-separated zwitterionic ground state. An efficient conversion of phenols into aryl halides is also reported.
创建时间:
2005-08-18



