A Chemoenzymatic Total Synthesis of the Protoilludane Aryl Ester (+)-Armillarivin
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/A_Chemoenzymatic_Total_Synthesis_of_the_Protoilludane_Aryl_Ester_Armillarivin/2422762
下载链接
链接失效反馈官方服务：
资源简介：
The title natural product, 1, has been synthesized in 20 steps from the enantiomerically pure cis-1,2-dihydrocatechol 2, itself obtained through the whole-cell biotransformation of toluene. The pivotal steps in the reaction sequence involve a Diels–Alder cycloaddition reaction between diene 2 and cyclopentenone (3) and the photochemically promoted 1,3-acyl rearrangement of the bicyclo[2.2.2]oct-4-en-1-one 20 derived from the cycloadduct 4.
创建时间：
2016-02-19
