Iridium(III)-Catalyzed C(3)–H Alkylation of Isoquinolines via Metal Carbene Migratory Insertion
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https://figshare.com/articles/dataset/Iridium_III_-Catalyzed_C_3_H_Alkylation_of_Isoquinolines_via_Metal_Carbene_Migratory_Insertion/16975605
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资源简介:
An Ir(III)-catalyzed C(3)–H
alkylation of N-acetyl-1,2-dihydroisoquinolines with
diverse acceptor–acceptor
diazo compounds has been achieved under a single catalytic system
via metal carbene migratory insertion. Moreover, further synthetic
transformations of the alkylated products such as aromatization, selective
decarboxylation, and decarbonylation lead to the formation of several
synthetically viable isoquinoline derivatives having immense potentials.
创建时间:
2021-11-10



