An Unusual Samarium Diiodide Mediated Reductive Ring Contraction of a Tricyclic Oxazine to a Highly-Functionalized Cyclopentane and Cyclobutane
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https://figshare.com/articles/dataset/An_Unusual_Samarium_Diiodide_Mediated_Reductive_Ring_Contraction_of_a_Tricyclic_Oxazine_to_a_Highly-Functionalized_Cyclopentane_and_Cyclobutane/3735114
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资源简介：
Samarium diiodide mediated reductive ring contraction of a substituted tricyclo[2.2.2]oxazine at 25 °C leads to a mixture of cyclopentane and
cyclobutane rearrangement products with complete diastereoselectivity in each case. At −78 °C, the anticipated amidocyclohexanol reduction
product is obtained exclusively, while the cyclopentane is the sole product at reflux in THF.
创建时间：
2016-08-20
