Catalytic Dual 1,1-H-Abstraction/Insertion for Domino Spirocyclizations

A catalytic domino spirocyclization of 1,7-enynes with simple cycloalkanes and cyclo-1,3-dicarbonyls has been established via multiple C–C bond formations from alkynyl/alkenyl functions and dual α,α-C­(sp3)-H abstraction/insertion. The reaction involves addition, 6-exo-dig cyclization and radical coupling sequences under convenient catalytic conditions and provides a concise access to spiro cyclopenta­[c]­quinolines in good to excellent yields.