Asymmetric β‑Boration of α,β-Unsaturated <i>N</i>‑Acyloxazolidinones by [2.2]Paracyclophane-Based Bifunctional Catalyst
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An efficient copper-catalyzed asymmetric conjugate boration has been achieved by exploiting a new planar and central chiral bicyclic triazolium ligand. This protocol was highly efficient and gave a variety of chiral secondary alkylboronates in 97–99% ee. A preliminary mechanistic study supports the bifunctional nature of the catalyst.
创建时间：
2012-11-16
