Porphyrin Synthesis in Water Provides New Expanded Porphyrins with Direct Bipyrrole Linkages: Isolation and Characterization of Two Heptaphyrins
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https://figshare.com/articles/dataset/Porphyrin_Synthesis_in_Water_Provides_New_Expanded_Porphyrins_with_Direct_Bipyrrole_Linkages_Isolation_and_Characterization_of_Two_Heptaphyrins/3221281
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The use of water for the porphyrin cyclization changes the products completely. Scandium-catalyzed aqueous condensation between pentafluorobenzaldehyde and pyrrole and subsequent oxidation provides novel expanded porphyrins with direct bipyrrole linkages, of which two novel heptaphyrins have been characterized by X-ray analyses.
创建时间:
2016-05-05



