Switching from Bonding to Nonbonding: Temperature-Dependent Metal Coordination in a Zinc(II) Sulfadiazine Complex
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The metal coordination in the mononuclear complex diamminebis(sulfadiazine)zinc shows a unique temperature dependence: High-resolution diffraction data prove that the coordination is almost tetrahedral at 100 K, whereas a fifth longer interaction becomes relevant at 200 K. The change in the geometry is fully reversible and is also reflected in the charge density of the compound.
创建时间：
2016-02-22
