Contrasting Behavior of Bis[2-(4,4-dimethyl-2-oxazolinyl)phenyl] Chalcogenides (Se/Te) toward Mercuric Chloride: Facile Cleavage of the Te−C Bond
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https://figshare.com/articles/dataset/Contrasting_Behavior_of_Bis_2_4_4_dimethyl_2_oxazolinyl_phenyl_Chalcogenides_Se_Te_toward_Mercuric_Chloride_Facile_Cleavage_of_the_Te_C_Bond/3355843
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资源简介：
The reactions of R2Se (3) and R2Te (4) (R = 2-(4,4-dimethyl-2-oxazolinyl)phenyl) with HgCl2
and Pd(COD)Cl2 are described. The reaction of selenoether 3 with HgCl2 affords the expected
complex R2SeHgCl2 (5), which is stable in solution. In contrast, the analogous tellurium
complex R2TeHgCl2 (6) undergoes slow dismutation in chlorinated solvents to give the
fragments RTeCl (7) and RHgCl (8).
创建时间：
2016-05-07
